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T.Y.B.Sc. Applied Component
Choice Based Credit System
SEMESTER V
PETROCHEMCALS
COURSE CODE: USACPET501 CREDITS: 02 LECTURES: 60
Unit -I
.1 The Chemistry of Petroleum Kingdom. (2L)
1.1.1 Compounds of Straight Run Gasolines.
1.1.2 Kerosene and Gas Oil Fractions.
1.1.3 Non -hydrocarbon Constituents
1.2 PETROLE UM EXPLORATION &
PRODUCTION. (7L)
1.2.1 Introduction
1.2.2 Formation of Oil and Gas
1.2.3 Characteristics of crude oils
1.2.4 Oils & Gas Exploration
1.2.5 Drilling for Oil and Gas
1.2.6 Production of Crude oil and Natural gas
1.3 Petroleum Products (6L)
1.3.1 Liquified Petroleum Gases (Composition, properties, extraction & Uses.)
1.3.2 Naphthas (Composition, Manufacture, properties & Uses.)
1.3.3 Kerosene (Composition, properties, extraction & Uses.)
1.3.4 Diesel Fuel (Composit ion, Properties & Uses)
Unit -II
2.1 INORGANIC CHEMICALS FROM PETROLEUM. (6L)
2.1.1 Sulphur byproducts
2.1.2 Hydrogen
2.1.3 Petroleum coke
2.1`4 Nitrogen compounds
2.2 REFIN ERY PROCESSES AND PRODUCTS.
2.2.1 Chemical Composition (2L)
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2.2.2 Distillation – separation based on relative volatilities – fractions obtained with flow
sheet diagrams . (2L)
2.2.3Conditions of conversion processes (catalyst, temperature , pressure etc.)
Mentioned below
–Pyrolysis, Catalytic cracking and hy drocracking, Isomerization, Alkylation,
Reforming (5L)
Unit -III
3. PREPARTION OF PETROCHEMICALS
3.1 From Propylene: (3L)
Isopropanol, cumene, glycerin, and acrylonitrile
3.2 From acetylene: (4L)
Vinyl chloride, Chloroprene, acrylonitrile and acetaldehyde
3.3 From C4 – hydrocarbons : (3L)
Butadiene, isobutene and butane
3.4 From aromatic hydrocarbon: (5L)
Aniline, chlorobenzene ,D.D.T, Xylene,
Unit -IV
4. Alternative sources for Fuels
4.1 Natural Gas (CNG) (3L)
4.2 Propane, Hydrogen & Alcohols (5L)
4.3 Biofuels (3L)
4.4 Other Fuels (2L)
4.5 Wind and solar Energy (2L)
PRACTICALS
SEMESTER V
PETROCHEMICALS
COURSE CODE: USACPET5P1 CREDITS: 02
I- APPLIED Experiments:
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Determination of Specific gravity and viscosity of Oil
To check the quality of Petrol
To check the quality of Diesel
II-Experiments (Demonstration) :
i) Cloud point
ii) Pour point
iii) Aniline point
III–Preparations:
1. Nitrobenzene to Dinitrobenzene.
2. Hydroquinone to Benzoquinone
3. Succinic acid into Succinic anhydride (Sublimation method)
SEMESTER VI
PETROCHEMICALS
COURSE CODE: USACHFC601 CREDITS: 02 LECTURES: 60
Unit -I
1.1 Chemicals from C 3, C4 and Higher Alkanes
1.1.1 Products from Propane (5L)
1.1.2 Chemicals from Propylene .
1.1.3 Derivatives of hydrocarbons Higher than Butanes.
1.2. General study of the following reactions use d in petrochemical industry (10L)
1. 2.1 Oxidation
1. 2.2 Ammoxidation
1. 2.3 Hydroformylation (oxo reaction)
1. 2.4 Hydration of olefins
1. 2.5 Chlorination
1.2.6 Polymerization (free radical and ionic)
Unit -II
2.1 Sources of higher olefins and aromatic hydrocarbons secondary materials from
petrochemicals with flow sheet diagrams. (5L)
2.2. UNIT OPERA TIONS (10L)
2.2.1 Extraction
2.2.2 Filtration
2.2.3 Crystallization
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2.2.4 Drying
2.2.5 Evaporation
2.2.6 Cooling
Unit -III
3.1 INDUSTRIAL CHEMICALS (7L)
3.1.1 Plastic: polyvinyl chloride, polystyrene.
3.1.2 Synthetic elastomers - styrene, Butadiene rubber, polychloroprene, nitrile rubber.
3.2 SYNTHETIC DETERGENTS (8L)
3.2.1 Introduction of Soap and Detergents
3.2.2 Classification of detergents
3.2.3 Surface active agents
3.2.4 Wetting agents
3.2.5 Emulsifying agents
3.2.6 Preparation of Dodecyl Benzene sulphate.
3.2.7 Finishing of Detergents
Unit -IV
Environmental pollution control in p etroleum refineries
4.1 Air pollution (6L)
4.1.1 Introducti on
4.1.2 Air Pollutants from refining operation
4.1.3 Air Pollution control technique
4.2 Water Pollution (6L)
4.2.1 Introduction of wat er pollution
4.2.2 Types of water pollution
4.2.3 Control of water pollution in petroleum refining.
4.2.4 Study of various parameters of polluted water.
4.3 Land Pollution (2L)
4.4 Carbon Credit (1L)
PRACTICALS
SEMESTER VI
PETROCHEMICALS
COURSE CODE: USACHFC6P1 CREDITS: 02
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I- Experiments
1. Determination of acid number of an oil.
2. Determination of acidity and alkalinity of given hydrocarbon
3. Estimation of Formaldehyde from given formalin sample
II- Applied Experiments (Demonstration) : -
i) Flash /fire point
ii) Calorific value of a fuel
iii) Steam Distillation
III – Preparations :
i) Benzoylation of β -naphthol
ii) Phthalic anhydride to phthalimide
iii) Cinnamic acid to dibromo cinnamic acid
IV- Industrial visit: Industrial visit report is to be incorporated in the journal
References:
1. Advanced Petroleum Refining, G. N. Sarkar
2. Petroleum Refining Technology, Dr. Ram Prasad
3. Petroleum Industries Technology and Process, Chhitta Ranjan Lahiri, Dipa Biswas.
4. A Text Book on Petro Chemicals, Dr. B. K. Bhaskararao.
5. A. I. Vogel: Text book of Quantitative Analysis including Instrumental Analysis.
6. A. I. Vogel : Text book of Quantitative Organic Analysis.
7. Advanced Practical Organic Chemistry 3rd Edition ,N.K.Vishnoi,Vikas Publication,
8. Practical Organic Chemistry by Mann and Saunders.
9. Vogel’s Textbook of Quantitative Chemical Analysis 5th Edition
10. Vogel's Qualitat ive Inorganic Analysis 5th Edition