T Y B Sc Three Units_1 Syllabus Mumbai University by munotes
Page 2
T. Y. B. Sc. CHEMISTRY (Three Units)
Credit Based and Grading System
To be impleme nted from the Academic year 2016 -2017
SEMESTER V
Theory
Paper -I
Course Un
it Contents Credit
s L/Week
USCHP501 1 1.1 Colligative Properties of Dilute Solutions (8L)
1.1.1 Dilute solution, colligate properties, Raoult’s law, relative
lowering of vapour pressure
1.1.2 Elevation in boiling point of a solution, thermodynamic
derivation relating elevation in the boiling point of a solution
and the molar mass of the non-volatile solute
1.1.3 Depression in freezing point of a solution, thermodynamic
derivation relating the depression in the freezing point of a
solution and the molar mass of the non -volatile solute.
1.1.4 Osmoti c pressure, van’t Hoff’s equation for osmotic
pressure, equation for osmotic pressure, determination of
molar mass of the solute. Abnormal molar masses of solutes
and van’t Hoff factor (calculation of Degree of Association
and Degree of Dissociation.)
1.2. Phase Rule
1.2.1. Gibb’s phase rule and terms involved in the
equation
1.2.2. Application of phase rule to ONE component
systems (i) water system, (ii) sulphur system
1.2.3. Application of phase rule to TWO component systems,
condensed systems, condensed phase rule, eutectic
systems (Lead -Silver system), desilverisation of lead
1.2.4. Introduction to three component system, explanation of
phase diagram for three liquids forming one i mmiscible
pair.
2.5 1
2 2.1.Electrochemistry –Electrochemical cells (15L)
2.1.1. Lewis concept of Activity and Activity coefficient, Mean
ionic activity and mean ionic activity coefficient γ +- of an
electrolyte, expression for activities of electrolytes of
different valence type, ionic strength
2.1.2. Classification of cells: 1.chemical cells without
transference 2.Concentration cells with and without
Transference (derivations of concentration cell EMF
expected) Origin of liquid -liquid junction potential and its
elimination using a salt bridge
2.1.3. Applications of EMF measurements in the determination
of 1. pH of a solution using quin hydrone electrode and
glass electrode. 2. Solubility and solubility product of
sparingly soluble salt using chemical cell and
concentrati on cell method. 3. Determination of liquid -
liquid junction potential
3 3. Chemical Bonding And Solid State Chemistry (15L)
Page 3
3.1 Molecular Symmetry (10L)
3.1.1 Introduction and Importance.
3.1.2 Symmetry elements and symmetry operations.
3.1.3 Concept of a Point Group with illustrations using the
following point groups: (i) Cαv (HCl), (ii) D αh (H2),
(iii) C 2v (H2O), (iv) C 3v (NH 3), (v) C 2h (trans –trichloroethylene),
and (vi) D 3h (BCl 3).
3.2 Molecular Orbital Theory for Polyatomic Species (5L)
3.2.1 Simple triatomic species: H 3+ and H3 (correlation between
bond angle and Molecular orbitals).
3.2.2 Other molecules (considering only σ -bonding): i) BeH 2, ii)
H2O.
4 Solution Chemistry
4.1 Acid -base Chemistry in Aqueous Medium (8L)
4.1.1 Acidity of mono - and polyatomic cations.
4.1.2 Basicity of mono - and polyatomic
anions ( discussion for 4.1.1 as well as 4.1.2 to Include Latimer
equation and predominance diagrams).
4.2 Chemistry in Non -aqueous Solvents (7L)
4.2.1 Classification of solvents and importance of non -aqueous
solvents.
4.2.2 Characteristics and study of liquid ammonia, dinitrogen
tetraoxide and acetic acid as non -aqueous solvent s with respect
to (i) acid -base reactions and (ii) redox reactions.
USCHP502 1 Mechanism of Organic Reactions (15L)
1.1. Thermodynamic and Kinetic control of organic reactions:
Concept with mechanisms of the following reactions: addition of
HX to butadiene; sulfonation of naphthalene. Nucleophilicity/
electrophilicity vs Basicity/acidity.
1.2 Mechanism o f elimination reactions, with stereochemistry:
E1 and E2 reactions: regioselectivity (Saytzeff and Hofmann
rules).
1.3 Mechanism of reactions of carbonyl compounds with
nucleophiles:
1.3.1 Formation of acetals/ketals from aldehydes and ketones.
1.3.2 Reac tion of aldehydes and ketones with primary and
secondary amines.
1.3.3 Acyl nucleophilic substitution (tetrahedral
mechanism): Acid catalysed esterification of Carboxylic acids
and base promoted hydrolysis of esters.
1.4 Mechanism of rearrangements with e xamples and
stereochemistry wherever applicable.
1.4.1 Migration to electron deficient carbon: Pinacol,
Benzylic acid.
1.4.2 Migration to deficient nitrogen: Beckmann, Hofmann.
1.5 Mechanism of the following react ons with synthetic
application: Claisen condensation, Michael addition. 2.5 1
2 Heterocyclic Chemistry (8L)
2.1.1 Introduction: Electronic structure and aromaticity of furan,
pyrrole,thiophene and pyridine.
Page 4
2.1.2 Synthesis: Synthesis of furans, pyrroles, and thiophenes by
Paal-Knor synthesis. Pyridines by Hantzsch synthesis and from
1,5-diketones.
2.1.3 Reactivity: Reactivity towards electrophilic substitution
reactions - of furan, pyrrole and thiophene on basis of stability of
intermediate; and of pyridine on the basis of electron
distribution.Nucleophilic substitution reaction of pyridine on the
basis of electron distribution.
2.1.4 Reactions of heterocycles: The following reactions of
furan, pyrrole and thiophene: Halogenation , Nitration,
Sulphonation, Vilsmeir formylation reactio n, Friedel -Crafts
reaction. Furan: Diels -Alder reaction. Ring opening of furan.
Pyrrole: Acidity and basicity of pyrrole -Comparison of basicity
of pyrrole and pyrrolidine, Acid catalysed polymerization of
pyrrole. Pyridine: Basicity. Comparison of basicit y of pyridine,
pyrrole and piperidine. Sulphonation of pyridine, with and
without catalyst. Reduction.Oxidation of alkyl pyridines and
action of sodamide (Chichibabin reaction).Nmethylation
of pyridine. Quaternization of piperdine, pyrrolidine and
Hofmann elimination of the quaternary salts.
2.2. Organic Synthesis (7L)
2.2.1 Introduction: Criteria for ideal organic synthesis. Yield and
selectivity. Multi - component synthesis – with examples,
Mannich reaction, Hanztsch synthesis of pyridines (without
mechanism).
2.2.2 Illustrative synthesis of industrially important compounds:
Ibuprofen (chiral synthesis), paracetamol (green synthesis),
Lascorbic acid (from D -glucose), norfloxacin, thyroxine,
vanillin, methyl dihydrojas monate (Hedione), Bifenox -I, pigment
red 242, indigo, 2 - hydroxy -3-amino -5-nitrobenzene sulphonic
acid.
2.2.3 Newer methods of organic synthesis: Introduction to the
use of the following in organic synthesis: Ultrasound,
microwaves, PTC.
3 Treatment of analytical data -I and sampling (15 L)
3.1 Treatment of Analytical Data (7L)
Types of errors, determinate and indeterminate errors,
minimization of errors, constant and proportionate errors,
accuracy and precision, measures of dispersion and central
tenden cy: mean, median, average deviation, relative average
deviation, standard deviation, variance,
coefficient of variation.[Numerical problems expected]
3.2 Sampling (8L)
Terms involved, importance of sampling, sampling techniques,
sampling of gases, ambient and stack
sampling, equipment used, sampling of homogeneous and
heterogeneous liquids, sampling of static and flowing liquids,
methods and equipments used, sampling of solids, importance of
particle size and sample size, samples used, need for the
Page 5
reductio n in the sample size, methods of reduction in sample
size, collection, preservation and dissolution of the sample.
Titri metric analysis -I and UV -Visible S pectroscopy. (15L)
4.1 Acid -base Titrations (5L)
Const ruction of titration curves and choice of indicators in the
titration of [1] strong acid and strong base, [2] strong acid and
weak base, [3] weak acid and strong base, [4] weak acid and
weak base.
4.2 Precipitation titrations (4L)
Argenti metric titrations, construction of the titration curve,
Volhard’s method, Mohr’s method, adsorption indicators, theory
and applications .
4.3 U.V. Visible Spectroscopy (4L)
Photometers and spectrophotometers, Instru mentation in the case
of single and double beam spectrophotometers, Qualita tive and
quantitative a nalysis, calibration cure method.
US3CHP05 Physical Chemistry Practicals Chemical Kinetics –
1. To determine the order between K2S2O8 &
KI by fractional change method.
Potentiometry –
2. To determine the solubility product and
solubility of AgCl potentiometrically using
chemical cell.
OR
3. To determine the solubility product and solubility of AgCl
potentiometrically using concentration cell.
Colorimetry –
To determine the amount of Fe(III) present in the given solution
by using salicylic acid by colorimetric titration.(static method)
( =525 nm)
Inorganic Chemistry Practicals
Inorganic preparations
1. Tris(en)2 Ni(II)S2O3
2. Tetra -amminecopper (II)Sulphate
Inorganic estimation/analysis
1. Ni complexometrically using Murexide Indicator 1.5
US3CHP06 Organic Chemistry Practicals
Binary Mixture Separation, drying, weighing & Melting Point
(No identification) (Solid + Solid) (4 Expts)
Analytical Chemistry Practicals
1. Estimation of persulphate in the given sample by the method
of back titratio n.
2. Determination of Vitamin C content of a
given tablet by titration with sodium hydroxide pH metrically
1.5
Page 6
T. Y. B. Sc. CHEMISTRY (Three Units)
Credit Based and Grading System
To be implemented from the Academic year 201 6-2017
SEMESTER VI
Theory
Paper -I
Course Unit Content Credi
ts L/Week
USC3CH601 1 Molecular Spectroscopy (15 L)
1.1 Dipole moment: Dipole moment, polarization of a
bond, bond moment, dipole moment and molecular
structure.
1.2 Rotational Spectrum: Rotational spectrum of a
diatomic molecule, rigid rotor, moment of inertia,
energy levels, conditions for obtaining pure rotational
spectrum, selection rule, nature of
pectrum, determination of inter nuclear distance and
isotopic shift.
1.3 Vibration ( IR ) spectrum:
Vibrational motion, degrees of freedom, modes of
vibration, vibrational spectrum of a diatomic molecule,
simple harmonic oscillator, energy levels, zero point
energy, conditions for obtaining vibrational spectrum,
selection rule, nature of spe ctrum.
1.4 Vibration -Rotation spectrum of
diatomic molecule
vibrating rotor, energy levels, selection rule, nature of
spectrum, R and P branches, anharmonic oscillator :
energy levels, selection rule, fundamental band,
overtones . Application of vibration rotation spectrum in
determining Force constant, determination and
significance. Introduction to infrared spectra of simple
molecules like H2O and CO2
1.5 Raman Spectroscopy : Scattering of
electromagnetic radiation, Rayleigh scattering, Raman
scattering, nature of Raman spectrum , Stoke’s
lines,anti - Stoke’s lines, Raman shift, quantum theory of
Raman spectrum, comparative study of IR and Raman
spectra, rule of mutual exclusion.(example of
CO2molecule). 2.5 1
2 2.1 Renewable Energy Sources (5L)
2.1.1. Lithium ion cell.
2.1.2 . Fuel cells; Choice of fuel and oxidant, Bacon’s
H2 and O2 fuel cell.
2.1.3 . Solar cells, solar energy, photovoltaicneffect,
semiconductors as solar energy converters, silicon solar
cell
Page 7
2.1.4 . Hydrogen : Fuel of the future,
production of hydrogen by direct electrolysis of water,
advantages of hydrogen as a universal energy medium.
2.2 Nuclear Magnetic Resonance
Spectroscopy (6L)
2.2.1 . Nuclear spin, magnetic moment, nuclear ‘g’
factor, energy levels, Larmor precession, Relaxa tion
processes in n.m.r. ( spin -spin relaxation and spin -lattice
relaxation).
2.2.2 . NMR Spectrometer, chemical shift, shielding and
deshielding of protons, low resolution n.m.r. spectrum
of methanol and ethanol.
2.3 Chemical Kinetics (4 L)
2.3.1 Collision theory of reaction rates,
application of collision theory to 1. unimolecular
reaction and 2. Bimolecular reaction ( Lindemann
theory, derivation expected). Merits and drawbacks of
collision theory.
2.3.2 Classification of reactions as slow, fast and ultra -
fast. study of kinetics of fast reactions by Stop flow
method.
3. Coordination Chemistry (15L)
3.1 Crystal Field Theory (CFT) (7L)
3.1.1 .Basic tenets of Crystal field theory and effect of
crystal field on central metal valence orbitals.
3.1.2 Splitting of d orbitals in octahedral,
tetrahedral and square planar complexes.
3.1.3 Crystal field splitting energy (10 / o) for
octahedral complexes and factors affecting the
magnitude of o.
3.1.4 Crystal field stabilization energy
(CFSE), calculation of CFSE, for octahedral and
tetrahedral complexes with d1 to d10 metal ion
configurations.
3.1.5 Effect of crystal field splitting on i)
Ionic radius and ii) Lattice energy.
3.1.6 Theoretical failure of the CFT model.
3.1.7 Exper imental evidence for co -valence in co-
ordination compounds.(i) ESR spectrum of [IrCl6]2 - (ii)
NMR spectrum of tris (acet yl acetanato) vanadium
complex, (iii) Intensities of d-d transitions, and (iv)
Nephelauxetic effect.
3.2 Molecular Orbital Theory (MOT) of
Coordination Complexes (4L)
3.2.1 Appl ication to octahedral complexes in case of (i)
[Ti(H2O)]3+, (ii) Fluoro complexes of Fe(II) and Fe
(III) and (iii) Cyano complexes of Fe(II) and Fe (III).
3.2.2 Effect of pi -bonding an ligand field
splitting parameter in M→L and L→M
Interactions .
Page 8
3.3 Electronic States and Terms for Poly electronic
Atoms (4L)
3.3.1 Introdu ction: electronic configuration and
electronic states, Term symbols, coupling of spin
momenta (Ms), orbital momenta (Ml)and spin- orbit
coupling or Russell -Saunders coupling.
3.3.2 Determination of Terms for p2 electronic
configuration (as in a carbon atom).
3.3.3 Terms and micro -states for transition metal
atoms/ions.
4. Some Selected Topics (15L)
4.1 Inorganic Polymers (3L)
4.1.1 Various methods of classification with
examples.
4.1.2 Chemistry of borazine with reference to
preparation, properties, structures,bonding and
applications.
4.2 Characteristics and Treatment of
Liquid Effluent (06L)
4.2.1 Characterization of wast e: biochemical oxygen
demand (BOD), chemical oxygen demand (COD), total
organic carbon (TOC), aerobic and anaerobic processes.
4.2.2 Removing of solid contaminants, physical and
chemical principles such as coagulation, flocculation
and sedimentation.
4.2.3 Primary,secondary and tertiary of liquid effluents.
4.3 Nanomaterials (04L)
4.3.1 Introduction and importance of nanomaterials.
4.3.2 Properties (Comparison between bulk and
nanomaterials): (i) Optical properties, (ii) Electrical
conductivity, and (iii) Me chanical properties.
4.3.3 Forms of nanomaterials: nanofilms, nanolayers,
nanotubes, nanowires, and nanoparticles.
4.3.4 Chemical methods of preparation: (i) Colloidal
route, and (ii) Sol -gel method.
4.4 Inorganic Pharmaceuticals (2L)
4.4.1 Gastrointestinal agents viz., (i) antacids
(aluminium hydroxide, milk of magnesia, sodium
bicarbonate and (ii) cathartics (magnesium sulphate and
sodium phosphate). Topical agents viz., (i) protectives
and adsorbents (talc, calamine), (ii) antimicrobial agents
(potassium permanganate, tincture iodine, boric acid )
and astringents (alum).
USC 3CH602
1. Spectroscopy (15L)
1.1 Introduction : Electromagnetic spectrum, units of
wavelength and frequency.
1.2 UV- Visible Spectroscopy: Basic theory, solvents,
nature of UV -VIS spectrum, concept of Chromophore,
auxochrome, bathochromic shift, Hypsochromic shift 2.5 1
Page 9
hyperchromic effect and chromophore - auxochrome
interactions.
1.3 IR Spectrocopy: Basic theory, nature of IR
spectrum, selection rule , fingerprint region.
1.4 PMR Spectroscopy: Basic theory of NMR, nature of
PMR spectrum, chemical shift (∂ unit), standard for
PMR, solvents used. Factors affecting chemical shift:
(1) inductive effect (2) anisotropic effect (with reference
to C=C, CΞC, C=O and benzene ring). Spin - spin
coupling and coupling constant. Proton exchange
application of deuterium exchange Application of PMR
in structure determination.
1.5 Spectral characteristics of following classes of
organic co mpounds, including benzene and
monosubstituted benzenes, with respect to UV -VIS,
IR,PMR: (1)alkanes (2)alkenes and polyenes (3) alkynes
(4) haloalkanes (5) alcohols (6) carbonyl compounds (7)
ethers (8) carboxylic acids (9) esters (10)amines (11)
amides (b road regions characteristic of different groups
are expected).
1.6 Problems of structure elucidation of simple organic
compounds using individual or combined use of the
above spectroscopic technique are expected.(index of
hydrogen deficiency should be the first step in solving
the problems).
2. 2.1 Organometallic Chemistry (5L)
2.1.1 Introduction : Carbon -metal bond - Nature, types
reactivity.
2.1.2 Organo magnesium Compounds : Grignard
reagent :Preparation , structure, and stability, Reaction
with compounds containing acidic hydrogen,carbonyl
compounds, cyanides and CO2.
2.1.3 Organolithium Compounds : Preparation using
alkyl/aryl halides. Reactions with compounds containing
acidic hydrogen, alkyl halides, carbonyl compounds,
cyanides and CO2. Lithium dialkyl cuprates:
Preparation and reactions with aliphatic
/aromatic/vinylic halides.
2.1.4 Organozinc compounds : Preparation of dialkyl
zinc. Reaction with water, acid chlorides and alkyl
halides. Reformatsky reaction (with mechanism).
2.2 Chemistry of some Important Biomolecules:
(10L)
2.2.1 α-Amino acids: Structure,configuration,Essential
amino acids a nd their abbreviations, classification,
Properties: pH dependency of ionic structure and
isoelectric point. Methods of preparations: Strecker
synthesis, amidomalonate synthesis, Erlenmeyer
azalactone synthesis.
Page 10
2.2.2 Polypeptides and Proteins: Polypeptides : Peptide
bond. Nomenclature and representation of polypeptides.
Merrifields solid phase peptide synthesis (example of
di- and tri - peptides for nomenclature and synthesis).
Proteins: Sources, types,functions,colloidal nature,
separation based on isoelect ric point, denaturation and
functions. Partial and total hydrolysis. General idea of
primary, secondary, tertiary and quartenary structures.
2.2.3 Nucleic acids: Selective hydrolysis of nucleic
acids.Sugars and bases in nucleic acids. Stuctures of
nucleosi des an nucleotides in DNA and RNA. Structure
of nucleic acids (DNA and RNA): Base pairing in
nucleic acids. Importance of nucleic acids -self
duplic ation, protein synthesis.
3. 3.1 Treatment of Analytical Data (6L): Distribution of
random errors, Gaussian curve, students’ t, confidence
limits and confidence interval, criteria for rejection of
result: 2.5d rule,4.0 rule and Q test, F teset, testing for
significance, null hypothesis, method of averages, least
squares method. [ Numerical problems expected]
3.2 Complexometric Titrations (5L): General
introduction, EDTA titrations, advantages and
limitations of EDTA as the titrant, absolute and
conditional formation constants of metal EDTA
complexes, construction of titration curves, types of
EDTA titrations,methods of increasing the selectivity of
EDTA as a titrant, metallochromic indicators, theory
and applications.
3.3 Redox Titrations (4L): General introduction, theory
of redox indicators, criterion for choosing an indicator
for a redox titrati on, construction of the titration
curves in the case of (1) Fe (II) Vs. Ce(IV ) (2) Fe (II)
Vs. dichromate, use of diphenyl amine and ferroin as
redox indicators. 2.5 1
4. Concepts in Quality and miscellaneous methods
(15L)
4.1 Total quality management ( 5L) : concept of quality,
quality control, quality assurance total quality
management, ISO series, Good laboratory practices
4.2 Mass Spectrometry (2L): Basic principles,
introduction of components only
4.3 Thermal Methods (5L): Classification of thermal
methods, thermogravimetric analysis,basic principles,
instrumentation factors affecting the TG curve,
applications
4.4 Introduction to Radio Analytical Techniques (3L):
Classification of the techniques, introduction to neutron
activation analysis and its applications. 2.5 1
Practicals
Page 11
US3CHP07 Physical Chemistry Practicals
Potentiometry –
1. To determine the strength of the given strong acid
(HCl) by potentiometric titration using quinhydrone
electrode (Calculation of pH from Ecell and the plot of
(a) against V (b) pH against V graphs are expected).
OR
2. To determine pKa value of the given weak monobasic
acid (CH3COOH) by e.m.f. measurements.
Conductometry –
3.To determine the amount of dibas ic acid (Oxalic acid)
by conductometric titration against strong base.
OR
4. To determine the relative strength of
monochloroacetic acid and acetic acid nductometrically.
Inorganic Chemistry Practicals
Inorganic preparations
1. Tris -(acetylacetonato) iron (III)
2. Bis -(Dimethylglyoximato) nickel (II)
Inorganic estimations/ Analysis
1. Acidity of a water sample.
1.5 4
US3CHP08 Organic Chemistry Practicals
Organic Preparations: Drying, Weighing
& Melting Point (No Purification)
1. Aniline/p -toluidine → N-Acetyl derivative
2. Salicylic acid/nitrobenzene/ Acetanilide →
Nitro derivative
3. β- naphthol → Methyl Ether derivative (Using
dimethyl sulphate)
4. Methyl salicylate/ethyl benzoate → Acid derivative
(Hydrolysis)
Analytical Chemistry Practicals
1. Dete rmination of chemical oxygen demand of a water
sample.
2. Determination of percentage purity of a sample of
common salt using a cation
exchanger.
3. Determination of acetic acid content of a vinegar
sample by potentiometric titration with sodium
hydroxide using quinhydrone. 1.5 4
Suggested References
Physical Chemistry
1. Physical Chemistry, Ira Levine, 5th Edition,
2002 Tata McGraw Hill Publishing Co.Ltd.
2. Physical Chemistry, P.C. Rakshit, 6th
Edition, 2001, Sarat Book Distributors,
Kolkota.
Page 12
3. Physical Chemistry, R.J. Silbey, & R.A.
Alberty, 3rd edition , John Wiley & Sons, Inc
[part 1]
4. Physical Chemistry, G. Castellan, 3rd
edition, 5th Reprint, 1995 Narosa Publishing
House.
5. Modern Electrochemistry, J.O.M Bockris &
A.K.N. Reddy, Maria Gamboa – Aldeco 2nd
Edition, 1st Indian reprint,2006 Springer
6. Visible & U.V. Spectroscopy, Analytical
Chemsitry by Open Learning R. Demny and
R. Sinclair M 1991 John Wiley & Sons
7. Classical Methods , Vol 1 Analytical
Chemistry by Open L earning D. Cooper &
C. Devan,1991 John Wiley & Sons
8. Physical Chemistry, G.M. Barrow, 6th
Edition, Tata McGraw Hill Publishing Co.
Ltd. New Delhi.
9. The Elements of Physical Chemistry, P.W.
Atkins, 2nd Edition, Oxford Universtity
Press Oxford
10. Physical Chemis try, G.K. Vemullapallie,
1997, Prentice Hall of India, Pvt.Ltd. New
Delhi.
Inorganic Chemistry.
1. D. Banerjea, Coordination chemistry, Tata
McGraw Hill, New Delhi, (1993).
2. D. F. Shriver and P. W. Atkins, Inorganic
chemistry, 3rd Ed., Oxford University Press,
(1999).
3. K. F. Purcell and J. C. Kotz, Inorganic chemistry,
Saunders, Hongkong, (1977).
4. N. N. Greenwood and E. Earnshaw, Chemistry of
elements, Pergamon Press, Singapore, (1989).
5. W. L. Jolly, Modern inorganic chemistry, 2nd Ed.
McGraw Hill Book Co., (1991).
6. B. E. Douglas and H. McDaniel, Concepts and
models in inorganic chemistry, 3rd Ed., John
Wiley & Sons, Inc., New York, (1994).
7. G. N. Mukherjee and A. Das, Elements of
bioinorganic chemistry, Dhuri and Sons,
Calcutta, (1988).
8. R. W. Hay, Bioinorganic chemistry, Ellis
Harwood, England, (1984).
9. R. C. Mehrotra and A. Singh, Organometallic
chemistry: A unified approach, Wiley Eastern,
New Delhi, (1991).
10. For synthesis of iron ethylenediamine sulphate
refer Practical Inorganic Chemis try by G. Marr
Page 13
and B. W. Rockett,Van Nostrand Reinhold
Company London1972. P 34.
11. For preparation of CuCl 2.2DMSO Refer
Microscale Inorganic Chemistry by Z. Szafran,
Ronald M. Pike and Mono M. Singh. Pub. John
Wiley and Sons1991.p.218.
Organic Chemistry
1. Organic Chemistry, Francis A Carey, Pearson
Education, 6th Edition, Special Indian Edition
2008
2. Organic Chemistry, R.T. Morrison and R.N.
Boyd, 6th Edition, Pearson Edition
3. Organic Chemistry, T.W.G. Solomon and C.B.
Fryhle, 8th Edition, John Wile y & Sons, 2004
4. A guide to mechanism in Organic Chemistry, 6th
Edition, Peter Sykes, Pearson Education
5. Fundamentals of Organic Chemistry , G. Marc
Loudon, 4th Edition Oxford
6. Organic Chemistry, L.G. Wade Jr and M.S.
Singh, 6th Edition,2008
7. Organic Chemistry Baula Y. Bruice, Pearson
Edition, 2008
8. Organic Chemistry,J.G. Smith, 2nd Editionm
Special Indian Edition, Tata McGraw Hill
9. Organic Chemistry, S.H. Pine, McGraw Hill
Kogakusha Ltd.
10. Stereochemistry, P.S. Kalsi, New Age
International Ltd. 4th Edition,2006
Analytical Chemistry
1. D. Harvey, Modern Analytical Chemistry, The
McGraw -Hill Pub. 1st Edition (2000)
2. H.S. Ray, R Sridhar and K.P. Abraham,
Extraction of Nonferrous Metals, AffiliatedEast -
West Press Pvt. Ltd. New Delhi (1985) reprint
2007.
3. G.H. Jeffery, J. Bassett, J. Mendham and R.C.
Denney , Vogel’s Textbook of Qunatitative
Chemical Analysis, Fifth edition, ELBS
Publication (1996)
4. D.A. Skoog D.M. West and F.J. Holler,
Fundametals of Analytical Chemistry,
7thEdition (printed in India in 20 01) ISBN
Publication.
5. Analytical Chemistry, J.G. Dick,1973 Tata
McGraw Hill Publishing Co. Ltd. New Delhi.
6. Quantitative analysis, Dey & Underwood,
Prentice Hall of India, Pvt. Ltd. New Delhi
Page 14
7. Fundamentals of Analytical Chemistry, Skoog
etal 8th edition, Sau nders college publishing.