## Chemical Engineering 1 Syllabus Mumbai University by munotes

## Page 2

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## Page 3

AC – 28/12/2021

Item No. - 6.10

UNIVERSITY OF MUMBAI

Bachelor of Engineering

(Chemical Engineering)

Direct Second Year (Sem. III) Admitted Students for the

current Academic Year 2021 -22 Only due to Covid

Pandemic

(REV - 2019 ‘C’ Scheme) from Academic Year 2019 – 20

Under

FACULTY OF SCIENCE & TECHNOLOGY

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University of Mumbai

Program Structure for B.E. Chemical Engineering (Revised 202 1-2022)

Semester III

Course

code Course Name

Teaching Scheme

(Contact Hours) Credits Assigned

Theory Practical Tutorial Theory Practical Tutorial Total

CHC301 Engineering Mathematics -III 3 - 1 3 - 1 4

CHC302 Industrial and Engineering

Chemistry I 3 - - 3 - - 3

CHC303 Fluid Flow Operations 3 - - 3 - - 3

CHC304 Chemical Engineering

Thermodynamics I 3 - - 3 - - 3

CHC305 Process Calculations 3 - - 3 - - 3

CHL301 Industrial and Engineering

Chemistry I Lab - 3 - - 1.5 - 1.5

CHL302 Fluid Flow Operation Lab - 3 - - 1.5 - 1.5

CHL303 Basic Chemical Engineering Lab - 3 - - 1.5 - 1.5

CHL304 Skilled Based Lab: Chemical

Technology Lab - 2*2 - - 2 - 2

CHM301 Mini Project 1A - 3# - - 1.5 - 1.5

Total 15 16 1 15 8 1 24

Course

code Course Name

Examination Scheme

Theory

Term

Work Pract/

Oral Oral Total Internal

Assessment End

Sem

Exam Exam

Duration

(in hrs) Test

1 Test

2 Avg

CHC301 Engineering Mathematics -III 20 20 20 80 3 25 - - 125

CHC302 Industrial and Engineering

Chemistry I 20 20 20 80 3 - - - 100

CHC303 Fluid Flow Operations 20 20 20 80 3 - - - 100

CHC304 Chemical Engineering

Thermodynamics I 20 20 20 80 3 - - - 100

CHC305 Process Calculations 20 20 20 80 3 - - - 100

CHL301 Industrial and Engineering

Chemistry I Lab - - - - 3 25 25 - 50

CHL302 Fluid Flow Operation Lab - - - - 3 25 25 - 50

CHL303 Basic Chemical Engineering Lab - - - - - 25 - 25 50

CHL304 Skilled Based Lab: Chemical

Technology Lab - - - - - 25 - 25 50

CHM301 Mini Project 1A - - - - - 25 - 25 50

Total - - 100 400 - 150 50 75 775

*Indicates Theory class to be conducted for full class

# indicates work load of Learner (Not Faculty), for Mini Project ;

faculty load : 1 hour per week per four groups , for Mini Project

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Semester III

Course Code Course Name Credits

CHC30 1 Engineering Mathematics III 04

Course Hours Credits Assigned

Theory Practical Tutorial Theory Practical Tutorial Total

03 - 01 03 - 01 04

Theory Term

Work/Practical/Oral

Total Internal Assessment End

Sem

Exam Duration of

End Sem

Exam

TW

PR

OR Test-I Test-II Average

20 20 20 80 03 Hours 25 - - 125

Prerequisites

Engineering Mathematics -I, Engineering Mathematics -II,

Course Objectives

1. To familiarize with the Laplace Transform, Inverse Laplace Transform of various

functions, its applications.

2. To acquaint with the concept of Fourier Series, its complex form and enhance the problem

solving skills.

3. To familiarize with the concept of complex variables, C -R equations with applications.

4. To study the application of the knowledge of matri ces and numerical methods in complex

engineering problems.

Detailed Syllabus

Module

No. Course Contents No. of

Hours.

01 Module: Laplace Transform

1.1 Definition of Laplace transform, Condition of Existence of Laplace

transform,

1.2 Laplace Transform (L) of Standard Functions like

( ) ( ) ( ) ( ) and .

1.3 Properties of Laplace Transform: Linearity, First Shifting theorem, Second

Shifting Theorem, change of scale Property, mult iplication by t, Division by

t, Laplace Transform of derivatives and integrals (Properties without proof).

1.4 Evaluation of integrals by using Laplace Transformation.

Self-learning topics: Heaviside’s Unit Step function, Laplace Transform. of

Periodic functions, Dirac Delta Function. 07

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02 Module: Inverse Laplace Transform

2.1 Inverse Laplace Transform, Linearity property, use of standard formulae to

find inverse Laplace Transform, finding Inverse Laplace transform using

derivative .

2.2 Partial fractions method & first shift property to find inverse Laplace

transform.

2.3 Inverse Laplace transform using Convolution theorem (without proof)

Self-learning Topics: Applications to solve initial and boundary value

problems involving ordinary d ifferential equations. 06

03 Module: Fourier Series:

3.1 Dirichlet’s conditions, Definition of Fourier series and Parseval’s Identity

(without proof)

3.2 Fourier series of periodic function with period 2π and 2l,

3.3 Fourier series of even and odd functions

3.4 Half range Sine and Cosine Series.

Self-learning Topics: Complex form of Fourier Series, orthogonal and

orthonormal set of functions, Fourier Transform. 07

04 Module: Complex Variables:

4.1 Function f(z) of complex variable, limit, continuity and differentiability of

f(z),

Analytic function, necessary and sufficient conditions for f(z) to be analytic

(without proof),

4.2 Cauchy -Riemann equations in cartesian coordinates (without proof)

4.3 Milne -Thoms on method to determine analytic function f(z) when real part

(u) or Imaginary part (v) or its combination (u+v or u -v) is given.

4.4 Harmonic function, Harmonic conjugate and orthogonal trajectories

Self-learning Topics: Conformal mapping, linear, biline ar mapping, cross

ratio, fixed points and standard transformations 07

05 Module: Matrices:

5.1 Characteristic equation, Eigen values and Eigen vectors, Properties of

Eigen

values and Eigen vectors. ( No theorems/ proof )

5.2 Cayley -Hamilton theorem (without proof): Application to find the inverse

of the given square matrix and to determine the given higher degree

polynomial matrix.

5.3 Functions of square matrix

5.4 Similarity of matrices, Diagonalizat ion of matrices

Self-learning Topics: Verification of Cayley Hamilton theorem, Minimal

polynomial and Derogatory matrix & Quadratic Forms (Congruent

transformation & Orthogonal Reduction) 06

06 Module: Numerical methods for PDE

6.1 Introduction of Partial Differential equations, method of separation of

variables, Vibrations of string, Analytical method for one dimensional heat

and wave equations. (only problems)

6.2 Crank Nicholson method 06

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6.3 Bender Schmidt method

Self-learning Topics: Analytical methods of solvi ng two and three

dimensional problems.

Course O utcomes

On successful completion of course learner/student will:

1. Apply the concept of Laplace transform to solve the real integrals in engineering

problems.

2. Apply the concept of inverse Laplace transform of various functions in engineering

problems.

3. Expand the periodic function by using Fourier series for real life problems and

complex engineering problems.

4. Find orthogonal trajectories and analytic function by using basic concepts of complex

variable theory.

5. Apply Matrix algebra to solve the engineering problems.

6. Solve Partial differential equations by applying numerical solution and analytical

methods for one dimensional heat and wave equations

Term Work

General Instructions:

1. Batch wise tutorials are to be conducted. The number of student’s per batch should be

as per University pattern for practical’s.

2. Students must be encouraged to write at least 6 class tutorials on entire syllabus.

3. A group of 4 -6 students should be assigned a self -learning topic. Students should

prepare a presentation/problem solving of 10 -15 minutes. This should be considered

as mini project in Engineering Mathematics. This project should be graded for 10

marks depending on the pe rformance of the students.

The distribution of Term Work marks will be as follows –

1. Attendance (Theory and Tutorial) 05 marks

2. Class Tutorials on entire syllabus 10 marks

3. Mini project 10 marks

Assessment

Internal Assessment Test:

Assessment consists of two class tests of 20 marks each. The first class test (Internal

Assessment I) is to be conducted when approx. 40% syllabus is completed and second

class test (Internal Assessment II) when additional 35% syllabus is completed. Duration

of each test shall be one hour.

End Semester Theory Examination:

1. Question paper will comprise of total 06 questions, each carrying 20 marks.

2. Total 04 questions need to be solved.

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3. Question No: 01 will be compulsory and based on entire syllabus wherein 4 sub -

questi ons of 5 marks each will be asked.

4. Remaining questions will be randomly selected from all the modules.

5. Weightage of each module will be proportional to number of respective lecture

hours as mentioned in the syllabus.

References

1. Engineering Mathematics, Dr. B. S. Grewal, Khanna Publication

2. Advanced Engineering Mathematics, Erwin Kreyszig, Wiley Eastern Limited,

3. Advanced Engineering Mathematics, R. K. Jain and S.R.K. Iyengar, Narosa

publication

4. Advanced Engineering Mathematics, H.K. Das, S. Chand Publicati on

5. Higher Engineering Mathematics B.V. Ramana, McGraw Hill Education

6. Complex Variables and Applications, Brown and Churchill, McGraw -Hill education,

7. Text book of Matrices, Shanti Narayan and P K Mittal, S. Chand Publication

8. Laplace transforms, Murray R. Spiegel, Schaum’s Outline Series .

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Semester III

Course Code Course Name Credits

CHC302 Industrial and Engineering Chemistry – I 03

Course Hours Credits Assigned

Theory Practical Tutorial Theory Practical Tutorial Total

03 - - 03 - - 03

Theory Term

Work/Practical/Oral

Total Internal Assessment End

Sem

Exam Duration of

End Sem

Exam

TW

PR

OR Test-I Test-II Average

20 20 20 80 03 H ours - - - 100

Prerequisites

1.Basic knowledge of Vander -Waal’s forces, various bonds, octet rule, resonance theory,

and hybridization.

2.Knowledge of periodic table, properties of transition metals, non -metals, oxidation state,

variable valency, basic functional groups etc.

3. XII class chemistry

Course Objectives

1.To study nomenclature, shapes, stability of coordination compounds and its applications.

2.To understand structures of different bio -molecules and stereochemistry of organic

molecules.

3. To study structure and bonding of organometallic compounds and its industrial

applications.

4. To study applications of electrochemistry conductometrically and potentiometrically and

solvent extraction technique.

5. To study the effect of temperature on stabi lity of reactive intermediate and their reaction

mechanism.

6. To understand importance of dyes, fertilizers and their effects.

Detailed Syllabus

Module

No. Course Content No of

Hours

01 Applications of Electrochemistry - 04

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Conductance, specific conductance, equivalent conductance, molar

conductance. Effect of dilution and temperature on conductance.

Transport number, moving boundary method and numerical.

Conductometry: Principle and types of titrations - Acid -base and

precipitation

02 Co-ordination chemistry & Organometallic compounds

Definitions: Co -ordination number/ligancy, Complex ion, Co -

ordination/dative bond. Nomenclature and isomerism (only

geometrical and structural) in co -ordination compounds w.r.t co -

ordination number 4 and 6. Effective Atomic Number (EAN) and

numericals. Crystal field theory (CFT), Application of CFT to

octahedral complexes and its drawbacks. Measurement of CFSE

(10Dq) and numericals. Applications of coordination compounds .

Organometallic compounds: Definition, metal clusters. Chemistry

of Fe -carbonyls [Fe (CO) 5] and [Fe 2(CO) 9 ] w.r.t preparation,

properties, structure and bonding . 08

03 Reaction pathways.

Difference between Transition state & intermediate. Equilibrium

(Thermodynamically) and Rate (Kinetically) controlled reactions -

explain w.r.t. sulphonation of naphthalene, Nitration of

Chlorobenzene, Friedel -Craft’s reaction. 03

04 Ion Exchange and solvent extraction techniques

Ion exchange resins, cation and anion exchangers. Desalination by

ion exchange and separation of lanthanides.

Liquid -Liquid solvent extraction, Nernst distribution law, distribution

ratio. Batch, continuous and counter current extraction. Numerical

based on solvent ex traction. 05

TOTAL 20

❖ One guest lecture from industry expert.

Course Outcomes

On completion of the course the students will:

1. Understand the different theories of chemical bonding, organometallic chemistry and

reactive intermediate.

2. Apply knowledge of dyes, fertilizers, analytical techniques of separation,

identification and quality of fertilizers.

3. Describe the reaction mechanisms, states of molecu les, various types of dyes and

reaction pathway in biological process.

4. Justify stability of coordination compounds, kinetics and energy of reactions and

importance of organometallic compounds in biological process.

5. Express role of biomolecules, eleme ntal constituents in fertilizers, and exchangers in

industries.

6. Apply concepts of electrochemistry and its applications quantitatively.

Assessment

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Internal Assessment (20 Marks) :

Consisting Two Compulsory Class Tests . First test based on approximately 40% of

contents and second test based on remaining contents (approximately 40% but excluding

contents covered in Test I).

End Semester Examination (80 marks) :

1. Weightage of each module in end semester examination will be proportional to

number of respective lectures.

2. Question paper will comprise of total six questions, each carrying 20 marks

3. Question 1 will be compulsory and should cover maximum contents of the

curriculum.

4. Remaining questions will be mixed in nature (for example if Q.2 has part (a) from

module 3 then part (b) will be from any module other than module3)

5. Only Four questions need to be solved .

Recommended Books

1.Engineering Chemistry - Jain& Jain Dhanpat Rai & Co. (P) Ltd

2.Engineering Chemistry - Satyaprakash & Manisha Agrawal, Khanna Book Publishing

3.Organic reaction Mechanisms - V.K. Ahluwalia , Rakesh Parashar, Narosa Publication

4. Industrial Chemistry – B K Sharma, Goel Publishing House

Reference Books

1. Principles of Physical Chemistry - B. R. Puri, L. R. Sharma, M.S. Pathania.

2. Principles of Inorganic Chemistry - Puri, Sharma, Kalia ,Milestone Publishers

3. Advanced Inorganic Chemistry – J. D. Lee

4. Organic Chemistry - I L Finar volume I and II.

5. Organic Chemistry – J. Clayden, Greeves, Warren, Wothers. Oxford university press

6. Principles Of Bioinorganic Chemistry - S.J. Lippard & J.M. Berg

7. Stereochemistry: Conformation and Mechanism by Kalsi, P.S, New Age International. Delhi

8. Stereochemistry of carbon compounds - Ernest Eliel, Tata McGraw Hill.

9. A textbook of Physical Chemistry - Glasston Sam uel, Macmillan India Ltd. (1991)

10. Technology of Textile Processing Vol. 2: Chemistry of Dyes and Principles of

Dyeing - Prof. V. A. Shena

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Course Hours Credits Assigned

Theory Practical Tutorial Theory Practical Tutorial Total

03 - - 03 - - 03

Theory Term

Work/Practical/Oral

Total Internal Assessment End

Sem

Exam Duration of

End Sem

Exam

TW

PR

OR Test-I Test-II Average

20 20 20 80 03 H ours -- -- -- 100

Students are assumed to have adequate background in physics, units and dimensions and

thermodynamics

1. Students should be able to understand the scope of the subject in chemical industry and

pressure drop - flow rate relationship.

2. They should be able to understand the boundary layer conditions and types of flow.

3. They should be able to understand the Bernoulli’s equation and its applications in

transportation of fluids.

4. They should be able understand the relation ship between pressure drop and flow rates in

conduits for incompressible fluids.

5. They should be able understand the types of velocities and stagnation properties for

compressible flow and viscosity using Stokes law.

6. They should be able understand the purp ose and need of power requirement in agitation

and selection and importance of pumps and valves.

Detailed Syllabus

Module

no. Course Contents No. of

Hours

1 Fluid and its properties, Newton’s law of viscosity, Kinematic

viscosity, Rheological behavior of fluid, Reynold’s experiment and

Reynold’s number, Laminar and turbulent flow in boundary layer,

Boundary layer formation in straight tube, Transition length for laminar

and turbulent flow. Boundary layer formation in straight tube,

Transition length for laminar and turbulent flow. 03

2 Bernoulli’s equation, Euler’s equation, Modified Bernoulli’s equation. 03 Semester III

Course Code Course Name Credits

CHC303 Fluid Flow Operations 03

Prerequisites

Course Objectives

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Practical Application of Bernoulli’s Equation (Venturimeter &

Orificementer)

3 Derivation of Hagen – Poiseullie equation, Friction factor, Darcy -

Weisbach equation, Moody diagram, Equivalent diameter for circular

and non -circular ducts. Major and minor losses 04

4 Flow of Compressible Fluids:

Mach number, Sonic, Supersonic and Subsonic flow, Continuity

equation and Bernoulli’s equation

Flow past immersed bodies:

Drag Forces, Coefficient of Drag, One dimensional motion of particle

through fluid, Terminal Settling Velocity, Stoke’s law, Stagnation

Point . 04

5 Classifiction of pumps, Centrifugal Pump - Construction & working,

Characteristics of pumps (curves), Cavitation, NPSH, NPSHA,

NPSHR, Priming.

Power Consumption in Agitation: Purpose of Agitation, Types of

Impellers, Prevention of Swirling, Power Curves, Power Number 04

TOTAL 18

Course Outcome s

On completion of the course the students will:

1. Acquire basic concepts and pressure measurement methods.

2. Learn kinematics of flow, rheological behavior of fluid and boundary layer conditions.

3. Learn Bernoulli’s equation and apply it in practical applications of various problems

in Chemical Engineering.

4. Learn flow equations and evaluate the losses in incompressible f low.

5. Learn the behavior of compressible fluids and Stokes Law and also able to apply

these concepts for estimation of stagnation properties.

6. Gain the knowledge of various pumps, choice of pumps, valves and agitators and

would be able to calculate power re quirement for pumps as well as for agitators.

Assessment

Internal Assessment (20 Marks) :

Consisting Two Compulsory Class Tests . First test based on approximately 40% of

contents and second test based on remaining contents (approximately) 40% but

excluding contents covered in Test 1).

End Semester Examination (80 marks) :

1. Weightage of each module in end semester examination will be proportional to

number of respective lectures .

2. Question paper will comprise of total six questions, each carrying 20marks .

3. Question 1 will be compulsory and should cover maximum contents of the

Curriculum.

4. Remaining questions will be mixed in nature (for example if Q.2 has part (a) from

Module 3 then part (b) will be from any module other than module3).

5. Only Four Q uestions need to be solved.

Recommended Books

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1.Warren L. Mccabe, Julian C. Smith, Peter Harriott, Unit Operations of Chemical

Engineering, McGraw Hill International Edition.

2. Coulson J. M., Richardson J. F., Backhurst J. R. and J. H. Harker, Chemical

Engineering, Vol. 1 and2.

3. Dr. R. K. Bansal, Fluid Mechanics and Hydraulic Machines, Laxmi Publications

Pvt.Ltd.

Reference Books

1. Cengel, Y. A. (2006). Fluid mechanics: fundamentals and applications. New Delhi,

India: Tata McGraw -Hill Publishing.

2. Darby, R. (2001). Chemical Engineering Fluid M echanics (2nd ed., rev.). New York:

Marcel Dekker.

3. Douglas, J. F. (2001). Fluid mechanics (5th ed.). New Delhi, India: Pearson Education

4. Batchelor, G. K. (1999). Introduction to Fluid Dynamics. New Delhi, India: Cambridge

University Press.

5. Rajput, R. K. (1998). A Textbook of Fluid M echanics. New Delhi, India: S Chand and co

6. Mohanty , A. K. (2009). Fluid M echanics (2nd ed.) . New Delhi, India: PHI Learning.

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Semester III

Course Code Course Name Credits

CHC304 Chemical Engineering Thermodynamics I 03

Course Hours Credits Assigned

Theory Practical Tutorial Theory Practical Tutorial Total

03 - - 03 - - 03

Theory Term

Work/Practical/Oral

Total Internal Assessment End

Sem

Exam Duration of

End Sem

Exam

TW

PR

OR Test-I Test-II Average

20 20 20 80 03 Hrs -- -- -- 100

1. Basic thermodynamic properties, laws and equations.

2.Engineering Mathematics : Differential and Integral Calculus, Linear Algebraic

Equations.

3. Engineering Physics and Engineering Chemistry.

1. To apply the first law of thermodynamics to chemical engineering syste ms.

2. To apply the second law of thermodynamics to chemical engineering systems.

3. To predict the P -V-T behavior of ideal gases and real gases.

4. To explain various thermodynamic concepts such as Entropy, Exergy and Fugacity.

5. To perform calculations involving the applications of the laws of thermodynamics to flow

processes.

6. To demonstrate the use of thermodynamic charts and diagrams.

Detailed Syllabus

Module

No Course Contents No. of

Hours

1 Review of First Law of Thermodynamics for flow and non flow

processes. 04

2 Concepts of heat engine, heat pump and refrigerator ,

Carnot Cycle and Carnot Principle 04

3 Concept of Exergy, Applications of Exergy 02 Prerequisites

Course Objectives

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4 Equations of state for non -ideal gases: van der Waals equation of

state. Redlich -Kwong equation of state. 03

5 Maxwell’s Equations , Enthalpy and Entropy departure functions (van

der Waals and Redlich -Kwong EOS ), Fugacity and fugacity

coefficient (van der Waals and Redlich -Kwong EOS) 06

TOTAL 19

Course Outcomes

On completion of the course the students will:

1. Apply the First Law of Thermodynamics to flow and non -flow Chemical Engineering

processes.

2. Compute the thermal efficiencies of various engines and machines using Second Law of

Thermodynamic and Entropy concepts.

3. Apply the concept of Exergy to engineering applications and utilize the laws of

thermodynamics to analy ze flow processes.

4. Compute the properties of real fluids using different equations of state.

5. Compute property changes of non -ideal gas systems using departure functions.

6. Use thermodynamic charts and diagrams for estimation of various thermodyn amic

properties.

Assessment

Internal Assessment (20 Marks) :

Consisting Two Compulsory Class Tests . First test based on approximately 40% of

contents and second test based on remaining contents (approximately 40% but excluding

contents covered in Test I).

End Semester Examination (80 marks) :

1. Weightage of each module in end semester examination will be proportional to number

of respective lectures.

2. Question paper will comprise of total six questions, each carrying 20 marks.

3. Question 1 will be compulsory and should cover maximum contents of the

curriculum.

4. Remaining questions will be mixed in nature (for example if Q.2 has part (a) from

module 3 then part (b) will be from any module other than module 3).

5. Only Four questions need to be solved.

Recommended Books

1. J.M. Smith, H.C. Van Ness, M.M. Abbot, M.T. Swihart, Introduction to Chemical

Engineering Thermodynamics, 8th Edition, McGraw -Hill Education, 2017.

2. K.V. Narayanan, A Textbook of Chemical Engineering Thermodynamics, 2nd Edition,

Prentice Hall of India Pvt. Ltd., 2013.

3. Y.V.C. Rao, Chemical Engineering Thermodynamics, Universities Press, 1997.

Reference Books

1. M.J. Moran, H.N. Shapiro, D.D. Boettner, M.B. Bailey, Fundamentals of Engineering

Thermodynamics, 9th Editio n, Wiley, 2018.

2. Gopinath Halder, Introduction to Chemical Engineering Thermodynamics, 2nd Edition,

Prentice Hall of India Pvt. Ltd., 2014.

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3. M.D. Koretsky, Engineering and Chemical Thermodynamics, John Wiley and Sons,

2009.

4. J. Richard Elliot and Car l T. Lira, Introductory Chemical Engineering

Thermodynamics, 2nd Edition, Prentice Hall, 2012.

Semester III

Course Code Course Name Credits

CHC305 Process Calculations 03

Course Hours Credits Assigned

Theory Practical Tutorial Theory Practical Tutorial Total

03 - - 03 - - 03

Theory Term

Work/Practical/Oral

Total Internal Assessment End

Sem

Exam Duration of

End Sem

Exam

TW

PR

OR Test-I Test-II Average

20 20 20 80 03 hours -- -- -- 100

1. Linear algebra

2. Differential equations

1

Familiarize various systems of units and conversion.

2 Learn about material balance of various unit operations for both steady and

unsteady state operations.

3 Understand the material balance of various unit processes.

4 To have the knowledge of recycle, bypass and purge operations.

5 Understand the energy balance calculations over various processes with and

without chemical reactions.

6 Development of the material balance and energy load of a binary distillation

column.

Detailed Syllabus

Module

No. Course Contents No. of

Hours

1 Introduction : Basic Chemical Calculations. Density, specific volume,

specific gravity, concentration & composition of mixtures and solutions.

Ideal Gas law, Dalton’s law, Amagat’s law and Raoult’s law. 02 Prerequisites

Objectives

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2 Material Balance without Chemical Reactions: Solving material

balance problems for various unit operations (Absorption, Distillation,

Extraction and C rystallization) 03

3 Material Balance with Chemical Reactions: Concept of limiting and

excess reactants, conversion and yield, selectivity and degree of

completion of reaction . 04

4 Recycle, Bypass and Purge Operations : Material Balance

calculations for both with and without chemical reactions. 02

5 Energy Balance: Heat capacity, sensible heat, latent heat, calculation of

enthalpy changes. General energy balance equation. Energy balances for

process involving chemical reaction including adiabatic reactions . 04

6 Combined Material and Energy Balance: Material and energy balance

for binary distillation . 01

TOTAL 16

Course Outcome

On completion of the course the students will:

1 Identify the various systems of units and conversion and apply principles of basic

chemical calculations .

2 Apply the material balance for various unit operations for both steady and unsteady

state operations .

3 Compute the material balance of various unit processes .

4 Evaluate recycle, bypass and purge operations and its streams .

5 Perform energy balance calcula tions over various processes with and without

chemical reactions .

6 Assess the material balance and energy load of a binary distillation column .

Assessment

Internal Assessment (20 Marks):

Consisting Two Compulsory Class Tests . First test based on approximately 40% of

contents and second test based on remaining contents (approximately 40% but excluding

contents covered in TestI).

End Semester Examination (80 marks):

1. Weightage of each module in end semester examination will be proportional to

number of respective lecture .

2. Question paper will comprise of total six questions, each carrying 20marks .

3. Question 1 will be compulsory and should cover maximum contents of the

curriculum.

4. Remaining questions will be mixed in nature (for ex ample if Q.2 has part (a) from

module 3 then part (b) will be from any module other than module3) .

5. Only Four questions need to be solved .

Recommended Books

1. Narayan, K. V. and Lakshmikutty, B. “Stioichiome try and Process Calculations”, 1stedition,

Prentice Hall of India Pvt. Ltd., New Delhi (2006)

2. Bhatt, B. I. and Thakore, S. B., “Stoichimetry, 5thedition , Tata McGraw Hill Education

Private Limited, New Delhi

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3. Ch. Durga Prasad Rao and D. V. S. Murthy, “Process Calculations for Chemical

Engineers”, McMillan India Ltd. (2010)

4. O. A. Hougen, K. M. Watson, and R. A. Ragatz., “Chemical process principles -part 1,

Material and Energy Balances”. Second Edition. John Wiley & Sons, Inc., New York

(1954).

Reference Books

1. Himmelblau, D. M. and Riggs, J. B., “Basic Principles and Calculations in Chemical

Engineering, 7 th edition, Prentice Hall of India Pvt. Ltd., New Delhi (2009)

Semester III

Course Code Course Name Credits

CHL301 Industrial and Engineering Chemistry Lab -I 1.5

Course Hours Credits Assigned

Theory Practical Tutorial Theory Practical Tutorial Total

- 03 - - 1.5 - 1.5

Theory Term

Work/Practical/Oral

Total Internal Assessment End

Sem

Exam Duration of

End Sem

Exam

TW

PR/OR

OR Test-I Test-II Average

- - - - - 25 25 -- 50

1. Basic knowledge of quantitative terms, Mole fractions, Normality, Morality etc.

2. Basic identification of salts, acids, bases, indicators etc.

3. Basic introduction of lab safety and handling of glass wares.

1. To enable students to prepare the standard solutions, carry out volumetric analysis to

check their accuracy and present the outcome of the experiment in statistical format to

calculate standard deviation.

2. To provide students an insight of titrimetry to determine contents of solution

quantitatively.

3. To enable students to apply knowledge of instrumental analysis to carry out acid -base

titrations without indicators , to calculate solubility product etc.

4. To make students learn the estimation of organic compound from given solution

quantitatively.

5. To make students understand the concept and importance of gravimetric analysis in

determination of amount of element in given solution.

6. To enable students carry out synthesis of chemicals by laboratory methods

Prerequisites

Lab Objectives

Lab Outcomes

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On completion of the course the students will:

1. Prepare standard solutions, check their accuracy and present results in statistical format

to calculate standard deviation.

2. Perform titrations and determine contents of solution quantitatively.

3. Apply knowledge of instrumental analysis like Conductometry and Potentiometry.

4. Learn methods of estimation of organic compounds quantitatively.

5. Carry out gr avimetric analysis systematically with proper understanding.

6. Carry out synthesis of chemicals in laboratory.

Experiment

no. Details of Experiment Lab

Hours

1 Volumetric analysis:

Preparation of standard solutions and to find normality, strength

and deviation factor. 3

2 Titrimetric analysis:

Analysis of talcum powder for Mg content by EDTA method 3

3 Potentiometric Titrations

Titration of strong acid and strong base potentiometrically. 3

4 Organic estimations

Estimation of phenol /Aniline 3

5 Gravimetric estimation of

Nickel as Ni D.M.G. 3

6 Preparation.

Preparation of Methyl Salicylate 3

7 Nitration of Aromatic compounds: Nitration of

Nitrobenzene/Acetanilide 3

Assessment

Term Work (25 marks) :

Distribution of marks will be as follows:

Laboratory work: 15 marks

Assignments: 05

Attendance: 05

End Semester Practical Examination/orals (25 marks) :

Practical Examination will be on experiments performed in the laboratory

Reference Books

1.Vogel’s Quantitative Chemical Analysis -David J. Barnes J. Mendham, R.C. Denney,

M.J.K Thomas Pearson Education; 6 edition

2. Laboratory Manual Engg. Chemistry - Anupma Rajput, Dhanpat Rai & Co.

3. Vogel’s Textbook of Practical organic chemistry.

List of Experiments (Minimum Five)

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Semester III

Course Code Course Name Credits

CHL302 Fluid Flow Operations Lab 1.5

Course Hours Credits Assigned

Theory Practical Tutorial Theory Practical Tutorial Total

- 03 - - 1.5 - 1.5

Theory Term

Work/Practical/Oral

Total Internal Assessment End

Sem

Exam Duration of End

Sem

Exam

TW

PR/OR

OR Test-I Test-II Average

- - - - - 25 25 - 50

1. Knowledge of physical sciences and units and dimensions.

2. Knowledge of properties of fluids, law of conservation of mass and law of momentum.

3. Knowledge of flow and pressure measurement devices.

4. Knowledge of different flow patterns and pumps.

Students should be able to:

1. Understand the basic properties and concepts of the fluid behavior in chemical industry.

2. Understand various flow patterns and boundary layer conditions.

3. Understand applications of flow and pressure measuring devices.

4. Understand various pipe fittings, valves and its applications.

5. Understand working and operations of various pumps.

6. Understand Working and application of agitated vessel and use of different impellers in

process industries.

Lab Outcome

On completion of the course the students will:

1. Determine viscosity by stokes law.

2. Distinguish different flow patterns and calculations involving Reynolds number.

3. Find coefficient of discharge for various flow measuring devices. Prerequisites

Lab Objectives

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4. Evaluate minor losses and frictional losses for various pipe fittings and network.

5. Calculate power required and efficiency for various pumps.

6. Find po wer requirement for various impellers in agitated vessel.

List of Experiments (Minimum Four )

Experiment

No. Details of Experiment Lab

Hours

1 To determine the coefficient of discharge for Orifice meter.

3

2 To determine minor losses in pipes.

3

3 To find out Reynolds number for the fluid flow using

Reynolds’s apparatus

3

4 To study the characteristics of centrifugal pumps.

3

5 To verify Bernoulli’s theorem.

3

6 To determine the coefficient of discharge for horizontal Venturi

meter.

3

Assessment

Term Work (25 marks) :

Distribution of marks will be as follows:

Laboratory work: 15 marks

Assignments: 05

Attendance: 05

End Semester Practical Examination/Orals (25 marks):

Practical Examination will be based on experiments performed in the laboratory.

Reference Books

1. Warren L. Mccabe, Julian C. Smith, Peter Harriott, Unit Operations of Chemical

Engineering, McGraw Hill International Edition.

2. Coulson J. M., Richardson J. F., Backhurst J. R. and J. H. Harker, Chemical

Engineering, Vol. 1 and 2.

3. Batchelor, G. K. (1999). Introduction to fluid dynamics. New Delhi, India: Cambridge

University Press.

4. Darby, R. (2001). Chemical engineering fluid mechanics (2nd ed., rev.). New York:

Marcel Dekker.

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Semester III

Course Code Course Name Credits

CHL303 Basic Chemical Engineering Lab 1.5

Course Hours Credits Assigned

Theory Practical Tutorial Theory Practical Tutorial Total

- 03 - - 1.5 - 1.5

Theory Term

Work/Practical/Oral

Total Internal Assessment End

Sem

Exam Duration of End

Sem

Exam

TW

PR/OR

OR Test-I Test-II Average

- - - - - 25 25 50

1. Knowledge of Inorganic, Organic and Physical Chemistry

2. Knowledge of Physics and

3. Knowledge of Mathematics

1. To understand basic chemical engineering concepts such as vapor pressure, surface

tension, heat of reaction, solubility, colligative properties etc.

2. To apply knowledge of chemistry to do experimental set up and carry out experiment

3. To understand different errors, sampling methods and sample size in laboratory

experiments.

4. To collect data after experiments

5. To study applications of experimental methods in practical situations

6. To become aware of industrially important reactions and operations

Lab Outcome s

On completion of the course the students will:

1. Apply basic principles of chemistry and chemical engineering to solve and analyze

complex industrial problems Prerequisites

Lab Objectives

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2. Apply mathematical skills to perform calculations on data obtained and use required

formulas to do the same

3. Evaluate sampling m ethods, required sampling size and reduce measurement errors for

accurate experimental design

4. Evaluate experimental data by different data analysis methods on PC using MS Excel for

investigating complex problems

5. Analyze and interpret the results obtained f rom experiments

6. Design new laboratory experiments to study industrial problems which will benefit

society and environment by following strict ethical standards

List of Experiments (minimum four )

Experiment

no. Details of Experiment Lab

Hours

1 Heat of reaction and Hess’s law of heat summation

3

2 Measurement of Dew Point Temperature

3

3 Demonstration of vapor pressure

3

4 Freezing point depression

3

5 Boiling point elevation

3

6 Limiting reactant and excess reactant for chemical reaction

3

Assessment

Term Work (25 marks) :

Distribution of marks will be as follows:

Laboratory work: 20 marks

Attendance: 05

End Semester orals (25 marks) :

Orals will be on experiments performed in the laboratory

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Course Code Course Name Credits

CHL30 4 Skilled based lab: Chemical Technology Lab 02

Course Hours Credits Assigned

Theory Practical Tutorial Theory Practical Tutorial Total

02 02 - 01 01 - 02

Theory Term

Work/Practical/Oral

Total Internal Assessment End

Sem

Exam Duration of End

Sem

Exam

TW

PR/OR

OR Test-I Test-II Average

- - - - - 25 - 25 50

1. Knowledge of Inorganic Chemistry .

2. Knowledge of Organic Chemistry .

3. Know ledge of Physical Ch emistry .

4. Knowledge of Physics and Mathematics.

1.To provide students an insight of different chemical processes and their engineering

problems.

2. To enable the students to understand the development of a process from its chemistry.

3. To equip students to draw and illustrate process flow diagrams.

4. To develop laboratory procedures for the preparation of industrially important chemicals

and products.

5. To enable students to be skilled in the practical aspects of synthesis of ch emicals.

6. To present the outcomes of laboratory experiments in the form of reports.

Course Outcome s

On completion of the course the students will:

1. Describe various manufacturing processes used in the chemical process industries. Semester III

Prerequisites

Course Objectives

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2. Explain industrial processing and overall performance of any chemical process including

the major engineering problems encountered in the process.

3. Draw and illustrate the process flow diagram for a given process.

4. Outline laboratory procedures for the preparation of industrially important chemicals and

products.

5. Plan and perform synthesis of important chemicals in the laboratory.

6. Demonstrate the ability to present scientific and technical information resulting from

laboratory experimentation and d raw conclusions from the results of the experiments.

Detailed Syllabus (theory 02 h ours per week)

Module

No. Course Contents No. of

Hours

1 Introduction :

Concept and brief description of the Unit Operations and Unit

Processes used in Chemical Industries

Overview of Industrially Important Products in the Chemical

Process Industries:

Soaps and Detergents 02

2 Natural Product Industries and Biodiesel Processing:

Manufacture of ethanol by fermentation of molasses

Biodiesel production by base -catalysed transesterification process 02

3 Manufacture of Acids:

Sulphuric Acid (DCDA Process), Nitric Acid

Manufacture of Fertilizers:

Urea 03

4 Chloro -Alkali Industries:

Manufacture of Caustic Soda

Manufacture of Soda Ash (Solvay Process ) 03

5 Basic Building Blocks of Petrochemical Industry:

Introduction to Petroleum Refining

Catalytic Cracking by Fluidized Catalytic Cracking Unit (FCCU) 02

6 Synthesis of Important Heavy Organic Chemicals and

Intermediates:

Manufacture of Cumene from benzene and propylene

Manufacture of Phenol from cumene by peroxidation -hydrolysis

process

Synthesis of Polymers:

Manufacture of Polyethylene: LDPE and HDPE

Manufacture of Nylon 66 02

TOTAL 14

List of Experiments (minimum six)

Experiment no. Details of Experiment Lab Hours

1 Preparation of Soap 2

2 Preparation of Alum from Alumin um 2

3 Preparation of Aspirin 2

4 Preparation of Methyl Orange 2

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5 Preparation of Thiokol R ubber 2

6 Preparation of Rubber Ball from Rubber Latex 2

7 Preparation of p -Bromo nitrobenzene from

Bromobenzene 2

Assessment

Term Work (25 marks) :

Distribution of marks will be as follows:

Laboratory work: 20 marks

Attendance (of theory and practical) : 05 marks

End Semester Orals (25 marks) :

Orals on topics covered in theory and experiments performed in the laboratory

Recommended Books

1.Rao, G.N. and Sittig M., Dryden’s Outlines of Chemical Technology for 21st Century,

East West Press, 3rd Edition, 1997.

2.Austin G.T., Shreve’s Chemical Process Industries, 5th Edition, McGraw Hill

International Edition, 1984.

3. Pandey, G.N., A Textbook of Chemical Technology, Vol. I and II, Vikas Publications,

1984.

4. B.K. Bhaskara Rao, Modern Petroleum Refining Processes, 6th Edition, Oxford and IBH

Publishing, 2020.

5.B.K. Bhaskara Rao, A Textbook of Petrochemicals, Khanna Publishers, 2004.

Reference Books

1.Kirk-Othmer’s Encyclopedia of Chemical Technology, John Wiley and Sons, Inc., 5th

Edition, 2007.

2.Ullmann’s Encyclopedia of Industrial Chemistry, Wiley -VCH, 7th Edition, 2011.

3.Alok Adholeya and Pradeep kumar Dadhich, Production and Technology of Biodiesel :

Seeding a Change, TERI Publication, New Delhi, 2008.

4. NIIR Board of Consultants and Engineers, The complete book on Jatropha (Biodiesel)

with Ashwagandha, Stevia, Brahmi and Jatamansi Herbs (Cultiv ation, Processing and

Uses), Asia Pacific Business Press Inc.

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Course Code Course Name Credits

CHM301 Mini Project 1A 1.5

Course Hours Credits Assigned

Theory Practical Tutorial Theory Practical Tutorial Total

- 03 - - 1.5 - 1.5

Theory Term

Work/Practical/Oral

Total Internal Assessment End

Sem

Exam Duration of End

Sem

Exam

TW

PR/OR

OR Test-I Test-II Average

- - - - - 25 - 25 50

Objectives

1. To acquaint with the process of identifying the needs and converting it into the

problem.

2. To familiarize the process of solving the problem in a group.

3. To acquaint with the process of applying basic engineering fundamentals to attempt

solutions to the p roblems.

4. To inculcate the process of self -learning and research.

Outcome: Learner will…

1. Identify problems based on societal /research needs.

2. Apply Knowledge and skill to solve societal problems in a group.

3. Develop interpersonal skills to work as member of a group or leader.

4. Draw the proper inferences from available results through theoretical/

experimental/simulations.

5. Analyse the impact of solutions in societal and environmental context for sustainable

evelopment.

6. Use standard norms of engineering practices

7. Excel in written and oral communication.

8. Demonstrate capabilities of self -learning in a group, which leads to life long learning.

9. Demonstrate project management principles during project work.

Guidelines for Mini Project

Students shall form a group of 3 to 4 students, while forming a group shall not be

allowed less than three or more than four students, as it is a group activity. Semester III

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Students should do survey and identify needs, which shall be conv erted into problem

statement for mini project in consultation with faculty supervisor/head of

department/internal committee of faculties.

Students hall submit implementation plan in the form of Gantt/PERT/CPM chart, which

will cover weekly activity of mini project.

A log book to be prepared by each group, wherein group can record weekly work

progress, guide/supervisor can verify and record notes/comments.

Faculty supervisor may give inputs to students during mini project activity; however,

focus shall be on self -learning.

Students in a group shall understand problem effectively, propose multiple solution and

select best possible solution in consultation with guide/ supervisor.

Students shall convert the best solution into working model using various c omponents

of their domain areas and demonstrate.

The solution to be validated with proper justification and report to be compiled in

standard format of University of Mumbai.

With the focus on the self -learning, innovation, addressing societal problems an d

entrepreneurship quality development within the students through the Mini Projects, it

is preferable that a single project of appropriate level and quality to be carried out in

two semesters by all the groups of the students. i.e. Mini Project 1 in semes ter III and

IV. Similarly, Mini Project 2 in semesters V and VI.

However, based on the individual students or group capability, with the mentor’s

recommendations, if the proposed Mini Project adhering to the qualitative aspects

mentioned above gets comple ted in odd semester, then that group can be allowed to

work on the extension of the Mini Project with suitable improvements/modifications or

a completely new project idea in even semester. This policy can be adopted on case by

case basis.

Guidelines for A ssessment of Mini Project:

Term Work

The review/ progress monitoring committee shall be constituted by head of departments

of each institute. The progress of mini project to be evaluated on continuous basis,

minimum two reviews in each semester.

In continu ous assessment focus shall also be on each individual student, assessment

based on individual’s contribution in group activity, their understanding and response to

questions.

Distribution of Term work marks for both semesters shall be as below;

o Marks awarded by guide/supervisor based on log book : 10

o Marks awarded by review committee : 10

o Quality of Project report : 05

Review/progress monitoring committee may consider following points for assessment

based on either one year or half year projec t as mentioned in general guidelines.

One-year project:

In first semester entire theoretical solution shall be ready, including components/system

selection and cost analysis. Two reviews will be conducted based on presentation given

by students group.

First shall be for finalisation of problem

Second shall be on finalisation of proposed solution of problem.

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In second semester expected work shall be procurement of component’s/systems,

building of working prototype, testing and validation of results based o n work

completed in an earlier semester.

First review is based on readiness of building working prototype to be conducted.

Second review shall be based on poster presentation cum demonstration of working

model in last month of the said semester.

Half -year project:

In this case in one semester students’ group shall complete project in all aspects

including,

o Identification of need/problem

o Proposed final solution

o Procurement of components/systems

o Building prototype and testing

Two reviews will be con ducted for continuous assessment,

First shall be for finalisation of problem and proposed solution

Second shall be for implementation and testing of solution.

Assessment criteria of Mini Project.

Mini Project shall be assessed based on following criteria;

1. Quality of survey/ need identification

2. Clarity of Problem definition based on need.

3. Innovativeness in solutions

4. Feasibility of proposed problem solutions and selection of best solution

5. Cost effectiveness

6. Societal impact

7. Innovativeness

8. Cost effectiveness and Societal impact

9. Full functioning of working model as per stated requirements

10. Effective use of skill sets

11. Effective use of standard engineering norms

12. Contribution of an individual’s as member or leader

13. Clarity in written and oral communica tion

In one year, project , first semester evaluation may be based on first six criteria’s and

remaining may be used for second semester evaluation of performance of students in

mini project.

In case of half year project all criteria’s in generic may be co nsidered for evaluation of

performance of students in mini project.

Guidelines for Assessment of Mini Project Practical/Oral Examination:

Report should be prepared as per the guidelines issued by the University of Mumbai.

Mini Project shall be assessed through a presentation and demonstration of working

model by the student project group to a panel of Internal and External Examiners

preferably from industry or research organisations having experience of more than five

years approved by head of Institution.

Students shall be motivated to publish a paper based on the work in

Conferences/students competitions.

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Mini Project shall be assessed based on following points;

1. Quality of problem and Clarity

2. Innovativeness in solutions

3. Cost effectiveness and Societal impact

4. Full functioning of working model as per stated requirements

5. Effective use of skill sets

6. Effective use of standard engineering norms

7. Contribution of an individual’s as member or leader

8. Clarity in written and oral comm unication